She was a leader at the Rivington Street Settlement in New York City, where she developed programs aimed at helping immigrants assimilate through educational, recreational, and vocational club activities.
At Rivington Street, Williams focused on improving the living and working conditions of the neighborhood's residents and emphasized the "Americanization" of immigrants.
She regularly reported to the CSA that these clubs functioned as "small republics," teaching practical measures and civic values of self-government.
[1] In 1896, Williams founded "Mount Ivy," a summer home community for the settlement located in Rockland County, New York.
This rural setting provided a place for immigrants to enjoy nature and reinforced the Americanization efforts of the Rivington Street Settlement.
[4] A group of her friends and colleagues took responsibility for the care and education of her adopted daughter, honoring Williams's dedication to improving others' lives.