[4] Masolin has a younger sister,[4] whom she was jealous of,[6] and she was taken by her father to watch sports events such as motor races and tennis matches in her youth to stop the two siblings from arguing.
[3][10] She was frequently sent to cover matches involving the Genoa CFC and UC Sampdoria clubs,[9] and subsequently presented the broadcaster's coverage of the 2011 Copa América.
[11] She made her first appearance as presenter at the 2014 Australian Grand Prix,[11] and has built a healthy working and personal relationship with fellow pundits Davide Valsecchi and 1997 world drivers' championship winner Jacques Villeneuve.
[6] Masolin presents the pre and post-race Paddock Live portions as well as the pre-race social column of Sky Sport's Formula One coverage.
[15] Masolin has been part of the Run That Track community raising money for foundations helping children in Bangladesh, Ghana and South Africa.