[1][5] Moylan took up a teaching position in Alexandria College from which she took a break in 1895 to study for a BSc through Queen's University Galway.

Moylan was part of the Central Association of Irish Schoolmistresses working to get permission for women to be admitted to Trinity College Dublin.

Moylan also worked on the need for training for secondary teachers in Ireland and on methods of teaching mathematics.

This established the Alexandra College Guild Tenement Company created to improve housing conditions in Dublin.

[1][6][7] By 1900 Moylan was studying for the Oxford University exams on the theory, history and practice of education.

She was expected to recover but died in the British Nursing Home in the Ismailia Quarter of Cairo on 15 June 1902.