Eventually he went into government service, working as Deputy Queen's Advocate for the Southern Circuit of Ceylon (modern Sri Lanka) in the mid-19th century.
He is perhaps best known for writing Ceylon and the Cingalese, a book published in two volumes in 1850 covering "their History, Government and Religion; the Antiquities, Institutions, Revenue and Capabilities of the Island; and a full Account of the late Rebellion; with Anecdotes illustrating the Manners and Customs of the People.
[3] He described his experiences in another book, China and the Chinese, subtitled: "Their religion, character, customs and manufactures; the evils arising from the opium trade; with a glance at our religious, moral, political and commercial intercourse with the country."
The book provides important contemporary insights into the nature of the opium trade and the endemic smuggling that took place in the Pearl River region.
Sirr, along with Paul Ivy Sterling was one of the first two barristers admitted to practice before the Supreme Court of Hong Kong at its first sitting on 1 October 1844.