Ionic strength

The total electrolyte concentration in solution will affect important properties such as the dissociation constant or the solubility of different salts.

Ionic strength can be molar (mol/L solution) or molal (mol/kg solvent) and to avoid confusion the units should be stated explicitly.

[1] The concept of ionic strength was first introduced by Lewis and Randall in 1921 while describing the activity coefficients of strong electrolytes.

For a 1:1 electrolyte such as sodium chloride, where each ion is singly-charged, the ionic strength is equal to the concentration.

Media of high ionic strength are used in stability constant determination in order to minimize changes, during a titration, in the activity quotient of solutes at lower concentrations.