For each atom, the column marked 1 is the first ionization energy to ionize the neutral atom, the column marked 2 is the second ionization energy to remove a second electron from the +1 ion, the column marked 3 is the third ionization energy to remove a third electron from the +2 ion, and so on.
"use" and "WEL" give ionization energy in the unit kJ/mol; "CRC" gives atomic ionization energy in the unit eV.
[1] As quoted at http://www.webelements.com/ from these sources: