His first appearance for the promotion was on November 28, 2005, as Jaymin Olivers, teaming with Brad Bradley against Val Venis and Viscera in a losing effort.
On July 13, 2010, he made appearance as Jamin Canseco at WWE Superstars teaming with Matt Cross losing to Curt Hawkins and Vance Archer.
He also appeared on the July 30 episode of Raw, used as one of the men in white taking Daniel Bryan to hospital, alongside fellow OVW wrestler Dylan Bostic.
In the beginning of 2008, Olivencia and Steel challenged Paul Burchill and Stu Sanders, but were unsuccessful in winning the OVW Southern Tag Team titles.
On October 15, Olivencia defeated Rudy Switchblade by forfeit, but lost it on the same day to Igotta Brewski.
Olivencia then started a feud with Brent Wellington, who won his OVW Television Championship on July 22.
[3] On June 2, 2012, Olivencia defeated Mohamad Ali Vaez to win the OVW Television Championship for the record-tying seventh time.
However, referee reverted the decision because Anthony didn't stop to apply his submission maneuver and Olivencia retained the title.
[11] Afterwards, Jamin would align himself with the returning Chris Silvio and the two would go on to capture The OVW Southern Tag Team Championship on the August 2 Saturday Night Special, defeating The Fabulous Free Bodies (The Bodyguy and Big Jon).
A month later, Silvi-O-livencia lost the titles to War Machine (Eric Locker & Shiloh Jonze) on September 6.
[15] On the November 23, 2011, edition of Ring of Honor Wrestling Olivencia faced Mike Bennett in a losing effort.
[18] The following night, Olivencia teamed with Jason Kincaid in a losing effort against Chase Owens and Sonjay Dutt.
[19] On July 10, 2015, during a GFW Grand Slam Tour event in Erie, Pennsylvania, Olivencia teamed with Jon Bolen in a losing effort against Sonjay Dutt and Moose.