Smogorzewski became the first metropolitan to be elected and confirmed following the Russian annexation of Polotsk where he was archbishop.
On 30 Oct 1780 he was selected as Metropolitan bishop of Kiev, Galicia, and all Ruthenia and was confirmed on 25 June 1781.
He consecrated the following bishops: Peter Bielański, Michael Stadnicki and Theodosius Rostocki.
Smogorzewski died in 1788 in Radomyshl where he started to build new metropolitan complex for the Ruthenian Church.
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