José Álvarez de Toledo y Dubois (14 May 1779 in Havana – 16 April 1858 in Paris) was a politician and leader of a military force against Spanish rule in Texas.
He was educated at the Escuela Naval de Cádiz and then joined the Spanish Navy in 1806.
Toledo was elected a representative of Santo Domingo to the Cortes of Cádiz.
Toledo then was one of the supporters of José Bernardo Maximiliano Gutierrez de Lara in his efforts for Mexico to secede from Spain.
Gutierrez's ancestors were among the first European Spanish settlers and colonizers in Mexico, Texas and surrounding areas.