She made her Fed Cup debut in February 2014, losing to Canada's Eugenie Bouchard in straight sets in their World Group II tie, but winning the dead doubles rubber the following day.

[3] Jović made her debut on the WTA Tour, qualifying for the main draw of the Monterrey Open and defeating Vera Dushevina in the first round.

Jović reached her first career WTA final at the Monterrey Open, losing to fellow Serb Ana Ivanovic in straight sets.

[4] In May, she made her Grand Slam main-draw debut at the French Open, losing in the first round to 31st seed Daniela Hantuchová, in three sets.

Only main-draw results in WTA Tour, Grand Slam tournaments, Olympic Games and Fed Cup/Billie Jean King Cup are included in win–loss records.