From then on, it crosses the streets Nemanjina, Birčaninova, Vojvode Milenka, Miloša Pocerca, Višegradska and Durmitorska.

[1] The assembly building was a humble, low and unrepresentative edifice, so sometimes the deputies held sessions in the "Kasina" hotel on the Terazije square.

The commercial zone, with grocery stores (čaršija), spread from Terazije to the street, while from this point on, the gardens and fields extended to the east until the marshy pond where the Slavija Square is today, where local population went for duck hunting.

Only after the Belgrade Main railway station was built in Bara Venecija in 1884, the stream was conducted underground and the Nemanjina was transformed into the proper street.

[6] The first traffic light in the Belgrade was placed at the crossroad of the Bulevar kralja Aleksandra, Takovska Street and the beginning of the Kneza Miloša in November 1939.

Instead, the second traffic light was placed only in 1953, in the neighborhood of London, at the crossroad of the Kneza Miloša and Maršala Tita (today Kralja Milana).

[10] The street gained somewhat of an assassination notoriety, due to the events connected with it, though they are results of the fact that most important government buildings are located in it.

[1][6] On the corner with Masarikova street, a Communist Spasoje Stević attempted to assassinate the king Alexander I of Yugoslavia in 1921.

[11] When prime minister Zoran Đinđić was assassinated on 12 March 2003 in front of the building of the government, he was rushed to the ER via the Kneza Miloša, but the wounds were fatal.

[1] In its first section, Kneza Miloša marks the border between Stari Grad and Vračar, until the intersection with Kraljice Natalije/Masarikova, where it enters Savski Venac.

During the 1998 façade cleaning of the building of the Ministry of the foreign affairs, Wehrmacht insignia were discovered below the surface layer.

In 2016 city government announced a detailed reconstruction of the Kneza Miloša, based on the look of one of the main Barcelona's avenues, Passeig de Gràcia.

[31] In September 2019, when reconstruction of the sidewalks was to begin, the works were moved for spring 2020, with a major change in the plan - the underground, elongated garages stretching for a kilometer, were dropped from the project.

In April 2020, during the outbreak of the coronavirus, new chief city urbanist Marko Stojčić sad that the project is moved to 2021–2022, not because of the pandemic, but because the construction is not ready anyway.

[33] However, deputy mayor Goran Vesić in September 2021 announced "serious reconstruction", with double avenues and a garage at the empty lot next to the Foreign Ministry building.

Investors from Cyprus envisioned a square edifice with "transparent" ground floor, which would allow a view from the street on the Hammam of Prince Miloš, which is on the other side of the building, in the Gavrilo Princip Park.

The decision provoked another negative public reaction, as it was part of the years long demolition of old buildings in Belgrade in order to accommodate investors.