Public education began in Liboje in 1885, and one of the former glass works buildings was converted into a school in 1922.

In March 1934 the miners in Liboje staged a hunger strike, and the local cell of the Communist Party was founded the same year.

[3] The local church is dedicated to Saint Agnes (Slovene: sveta Neža) and belongs to the Parish of Griže.

[3] The current structure incorporates the bell tower, sacristy, and chancel of the old church with a new nave built between 1985 and 1999.

[5] Notable people that were born or lived in Liboje include: This article about the Municipality of Žalec in Slovenia is a stub.