She is known for playing Valerie Birkhead on Sabrina the Teenage Witch (1997–99) and Emily in The Odd Couple (2015–17).

She auditioned unsuccessfully for many roles in a number of television shows including Blossom and Full House.

Sloane was featured in the seventh season of Weeds, playing Maxeen, a character who hires Silas for a modeling gig and dates Andy.

Most recently, she appeared in the main cast of the CBS sitcom The Odd Couple as Emily.

[6] Her film résumé includes roles in Bring It On, Exposed, The In-Laws, Nancy Drew, Sabrina Down Under, Over Her Dead Body, She's Out of My League, The Other Guys and The Accidental Husband.