Located in the northern part of the county, it borders the following townships and city: No municipalities are located in Liverpool Township, although the unincorporated community of Valley City is located in the center of the township.

The "Frog Jump Capital of Ohio," it lies at the intersection of State Routes 303 (Center Road) and 252 (Columbia Road).

Liverpool Township is located between 20 and 30 miles south of Lake Erie and about five miles west of Interstate 71.

[4] Statewide, the only other Liverpool Township is located in Columbiana County.

The township is governed by a three-member board of trustees, who are elected in November of odd-numbered years to a four-year term beginning on the following January 1.