With others of his colleagues he was in 1850 brought to trial for having taken part in organizing a movement for refusal to pay taxes; he was condemned to fifteen months imprisonment in a fortress, but left the country before the sentence was executed.
For ten years he lived in exile, chiefly in London; he acted as special correspondent of the National Zeitung, and gained a great knowledge of English life; and he published a work, Der Parliamentarismus wie er ist, a criticism of parliamentary government, which shows a marked change in his political opinions.
In 1860, Bucher returned to Germany, and became intimate with Ferdinand Lassalle, who made him his literary executor.
It was Bucher who drew up the text of the constitution of the North German Confederation; in 1870 he was sent on a confidential mission to Spain in connection with the Hohenzollern candidature for the Spanish crown , (although Eyck states that it was in fact the Prussian diplomat and historian Theordor von Bernhardi); he assisted Bismarck at the final negotiations for the Treaty of Frankfurt, and was one of the secretaries to the Congress of Berlin; he also assisted Bismarck in the composition of his memoirs.
He identified himself completely with Bismarck's later commercial and colonial policy, and probably had much to do with introducing it, and he did much to encourage anti-British feeling in Germany.