The album features production by several musicians, including Jean-Pierre Taïeb, Frédéric Jaffré and Niels Brinck.

Luminescence was certified gold in Russia, while the album's singles accumulatively received more than 79,000 plays on Russian radio according to TopHit.ru.

She collaborated with Swedish musician Jörgen Elofsson and Canadian rock singer Bryan Adams, whom she first met while performing at the 2000 Christmas concert in Vatican.

She restarted the production of her third international studio album with several producers, including Jean-Pierre Taieb and Frederic Jaffre as well as Niels Brinck.

In 2006, both English and French version of Luminescence were re-released with three additional tracks, "I'll Be Alright" ("Juste avant toi"), "A Crime" ("Garde Moi") and "Waiting" ("Quelqu'un").