She was previously an assistant coach for the Penn State Nittany Lions women's ice hockey program.

Across 144 NCAA games with the Quinnipiac Bobcats women's ice hockey program, Samoskevich scored 109 points, the fourth highest total in the university's history.

She would sign her first professional contract with Brynäs IF Dam in the Swedish Women's Hockey League (SDHL) for the 2019–20 season, but would only play 8 games with the club before leaving due to homesickness.

[6] On August 18, 2020, Samoskevich was announced as a new assistant coach for the Penn State Nittany Lions women's ice hockey program.

[19] Her sister, Madison, represented the United States at the 2019 IIHF World Women's U18 Championship and, since the 2020–21 season, plays as a defenseman with the Quinnipiac Bobcats ice hockey program.