Montenero d'Orcia is a village in Tuscany, central Italy, administratively a frazione of the comune of Castel del Piano, province of Grosseto, in the area of Mount Amiata.

At the time of the 2001 census its population amounted to 253.

[1] Montenero is about 44 km from Grosseto and 14 km from Castel del Piano, and it is situated on a hill between the valley of Orcia and Ombrone rivers.

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