Moscovium

This is an accepted version of this page Moscovium is a synthetic chemical element; it has symbol Mc and atomic number 115.

In December 2015, it was recognized as one of four new elements by the Joint Working Party of international scientific bodies IUPAC and IUPAP.

Moscovium is calculated to have some properties similar to its lighter homologues, nitrogen, phosphorus, arsenic, antimony, and bismuth, and to be a post-transition metal, although it should also show several major differences from them.

Chemical experimentation on single atoms has confirmed theoretical expectations that moscovium is less reactive than its lighter homologue bismuth.

[24] The definition by the IUPAC/IUPAP Joint Working Party (JWP) states that a chemical element can only be recognized as discovered if a nucleus of it has not decayed within 10−14 seconds.

Headed by Russian nuclear physicist Yuri Oganessian, the team included American scientists of the Lawrence Livermore National Laboratory.

[56] The Dubna–Livermore collaboration strengthened their claim to the discoveries of moscovium and nihonium by conducting chemical experiments on the final decay product 268Db.

In June 2004 and December 2005, the presence of a dubnium isotope was confirmed by extracting the final decay products, measuring spontaneous fission (SF) activities and using chemical identification techniques to confirm that they behave like a group 5 element (as dubnium is known to be in group 5 of the periodic table).

[3][57] Both the half-life and the decay mode were confirmed for the proposed 268Db, lending support to the assignment of the parent nucleus to moscovium.

Another evaluation of more recent experiments took place within the next few years, and a claim to the discovery of moscovium was again put forward by Dubna.

[59] In August 2013, a team of researchers at Lund University and at the Gesellschaft für Schwerionenforschung (GSI) in Darmstadt, Germany announced they had repeated the 2004 experiment, confirming Dubna's findings.

[63] In December 2015, the IUPAC/IUPAP Joint Working Party recognized the element's discovery and assigned the priority to the Dubna-Livermore collaboration of 2009–2010, giving them the right to suggest a permanent name for it.

The decay chains assigned to 289Mc, the isotope instrumental in the confirmation of the syntheses of moscovium and tennessine, were found based on a new statistical method to be too different to belong to the same nuclide with a reasonably high probability.

The reported 293Ts decay chains approved as such by the JWP were found to require splitting into individual data sets assigned to different tennessine isotopes.

The multiplicity of states found when nuclides that are not even–even undergo alpha decay is not unexpected and contributes to the lack of clarity in the cross-reactions.

[65][66] On June 8, 2017, two members of the Dubna team published a journal article answering these criticisms, analysing their data on the nuclides 293Ts and 289Mc with widely accepted statistical methods, noted that the 2016 studies indicating non-congruence produced problematic results when applied to radioactive decay: they excluded from the 90% confidence interval both average and extreme decay times, and the decay chains that would be excluded from the 90% confidence interval they chose were more probable to be observed than those that would be included.

Although widely used in the chemical community on all levels, from chemistry classrooms to advanced textbooks, the recommendations were mostly ignored among scientists in the field, who called it "element 115", with the symbol of E115, (115) or even simply 115.

[12] The naming ceremony for moscovium, tennessine, and oganesson was held on 2 March 2017 at the Russian Academy of Sciences in Moscow.

[74] In 2024, the team at JINR reported the observation of one decay chain of 289Mc while studying the reaction between 242Pu and 50Ti, aimed at producing more neutron-deficient livermorium isotopes in preparation for synthesis attempts of elements 119 and 120.

[75] Such reactions have been proposed as a novel synthesis route for yet-undiscovered isotopes of superheavy elements with several neutrons more than the known ones, which may be closer to the theorized island of stability and have longer half-lives.

Possible drawbacks are that the cross section of the production reaction of 295Ts is expected to be low and the decay properties of superheavy nuclei this close to the line of beta stability are largely unexplored.

[78] Other possibilities to synthesize nuclei on the island of stability include quasifission (partial fusion followed by fission) of a massive nucleus.

[78] One last possibility to synthesize isotopes near the island is to use controlled nuclear explosions to create a neutron flux high enough to bypass the gaps of instability at 258–260Fm and at mass number 275 (atomic numbers 104 to 108), mimicking the r-process in which the actinides were first produced in nature and the gap of instability around radon bypassed.

[78] Some such isotopes (especially 291Cn and 293Cn) may even have been synthesized in nature, but would have decayed away far too quickly (with half-lives of only thousands of years) and be produced in far too small quantities (about 10−12 the abundance of lead) to be detectable as primordial nuclides today outside cosmic rays.

However, notable differences are likely to arise; a largely contributing effect is the spin–orbit (SO) interaction—the mutual interaction between the electrons' motion and spin.

It is especially strong for the superheavy elements, because their electrons move much faster than in lighter atoms, at velocities comparable to the speed of light.

Unlike the two previous 7p elements, moscovium is expected to be a good homologue of its lighter congener, in this case bismuth.

However, for bismuth it becomes rare due to the relativistic stabilization of the 6s orbitals known as the inert-pair effect, so that the 6s electrons are reluctant to bond chemically.

[4] Mc3+ should be about as stable as Tl3+ and hence should also be an important part of moscovium chemistry, although its closest homolog among the elements should be its lighter congener Bi3+.

[4] Moscovium(III) fluoride (McF3) and thiozonide (McS3) should be insoluble in water, similar to the corresponding bismuth compounds, while moscovium(III) chloride (McCl3), bromide (McBr3), and iodide (McI3) should be readily soluble and easily hydrolyzed to form oxyhalides such as McOCl and McOBr, again analogous to bismuth.

A graphic depiction of a nuclear fusion reaction
A graphic depiction of a nuclear fusion reaction. Two nuclei fuse into one, emitting a neutron . Reactions that created new elements to this moment were similar, with the only possible difference that several singular neutrons sometimes were released, or none at all.
Apparatus for creation of superheavy elements
Scheme of an apparatus for creation of superheavy elements, based on the Dubna Gas-Filled Recoil Separator set up in the Flerov Laboratory of Nuclear Reactions in JINR. The trajectory within the detector and the beam focusing apparatus changes because of a dipole magnet in the former and quadrupole magnets in the latter. [ 39 ]
A view of the famous Red Square in Moscow . The region around the city was honored by the discoverers as "the ancient Russian land that is the home of the Joint Institute for Nuclear Research" and became the namesake of moscovium.
The expected location of the island of stability. The dotted line is the line of beta stability .