Natalia Galibarenko graduated from Taras Shevchenko National University of Kyiv, master's degree in International Relations; Languages: English and Spanish.

2006-2007 – Chief Consultant of the Main Office for Foreign Policy, European and Euro-Atlantic Integration Processes of the Presidential Administration of Ukraine.

2012-2014 – Deputy Head of the Permanent Mission of Ukraine to the International Organizations in Vienna.

She participated in numerous bilateral and multilateral negotiations of Ukraine, including in framework of the EU, Council of Europe, OSCE and other international organizations.

From 2015 — Ambassador Extraordinary and Plenipotentiary of Ukraine to the United Kingdom of Great Britain and Northern Ireland, Permanent Representative to the IMO.