In 1998, she started working as the deputy director of the Collegium № 11 of Chernihiv, she was a member of the Commission of the City Department of Education and Science.
From 2001 to 2006, she worked as an assistant-consultant to the People's Deputy of Ukraine, chairman of the Verkhovna Rada Committee on Legal Policy Vasyl Onopenko, and was actively involved in politics.
Since 2006, Romanova has been a member of the Permanent Delegation of Ukraine to the House of Congress of Local and Regional Authorities of the Council of Europe.
In 2008, she graduated with honors from the National University Odesa Law Academy with a degree in civil and commercial justice.
137-k (with changes and additions to the order of the head of the regional state administration dated 12 December 2017 G. 443-k), Natalia Romanova was appointed Deputy Governor of Chernihiv Oblast.