[1] The hour-long show usually features a single guest related to an important political, cultural or economic event that came to light recently.

A number of prominent Croatian and international politicians, artists, musicians, scientists and athletes have appeared on the show, some to much ensuing media coverage and controversy after the fact.

The show, which first aired on 8 October 2000 with Ivo Sanader as guest, underwent some format changes throughout the years.

Nedjeljom u dva quickly became one of the most popular HRT shows, mostly due to Stanković taking a polemical approach towards his guests.

Notable guests include Zdravko Mamić, Zoran Milanović, Milan Bandić, Lepa Brena, Goran Bare, Slavoj Žižek, Toni Kukoč, Rambo Amadeus, Ivo Josipović, Mira Furlan, Boris Tadić, Boris Dvornik, Ivan Gašparovič, Garry Kasparov, Emir Kusturica, Kolinda Grabar-Kitarović, Mirko Filipović, Dan Brown, and Tomislav Tomašević.