Simões played for 10 years at Portuguese Campeonato Nacional Feminino club Escola, before transferring to German Frauen-Bundesliga team SC 07 Bad Neuenahr in July 2012.
[4][5] Simões had been scouted by SC 07 whilst playing in the 2012 Algarve Cup,[4] and signed a one-year contract.
FC Köln,[6] before returning to Portugal to play for Campeonato Nacional Feminino club Valadares Gaia F.C.
[8] In 2019, Simões helped Valadares to beat Clube de Albergaria in a penalty shoot-out to progress to the Portuguese Women's Cup Final.
[10] They lost the match 4–0, and Simões went off injured after 86 minutes, and had to be replaced in goal by an outfield player.