Daniele recognized his talent and persuaded De Giosa's father to enroll him at the Conservatory of San Pietro a Majella in Naples.
He passed the entrance examination at age 14 with sufficient merit to be awarded free tuition at the conservatory and continued his flute studies there with Pasquale Bongiorno.
In 1839, while still a student, two of his compositions for soloists, chorus and orchestra were performed at the conservatory in honour of Count Wenzel Robert von Gallenberg who had died in March of that year.
However, in 1841 he left San Pietro a Majella without completing his studies following a series of disputes with the Saverio Mercadante who succeeded Zingarelli as the conservatory's director in 1840.
It had a run of 98 consecutive performances at the Teatro Nuovo where it premiered in 1850 and was regularly produced in numerous opera houses in Italy and abroad over the next 40 years.
According to Giovine, De Giosa eventually replaced his lost savings with the money he earned from his successful conducting career.
The project was a protest against the "invasion" of Neapolitan opera stages by French operetta at the expense of the city's native musical culture.
Set in a working-class neighbourhood of Naples at Carnival time, it recounts the ultimately successful campaign by Temostocle, nephew of the wealthy and pretentious Don Gasperone, to marry the daughter of a shoemaker.
During this time De Giosa was also active as a teacher at the Conservatory of San Pietro a Majella and in organizations dedicated to the encouragement of young musicians and composers.
[9][10][11] Most of De Giosa's sacred music was composed during his time at the San Pietro a Majella conservatory including four masses, three of them messe di gloria, and a Dixit Dominus.