Night King

[4] Regarding whether the character in the television series is the same as the one in the novels, Martin said, "As for the Night's King (the form I prefer), in the books he is a legendary figure, akin to Lann the Clever and Brandon the Builder, and no more likely to have survived to the present day than they have.

"[5] Makeup artist Barrie Gower said the Night King used mostly practical prosthetic, but also incorporates some visual effects (VFX) to create a more icy look and feel.

[6] In the sixth season he was portrayed by Vladimir Furdik after Brake was forced to drop out due to scheduling conflicts stemming from his participation in the TV series The Bastard Executioner.

[7][8] The White Walker army was first shot in front of a green screen in Magheramorne quarry, and according to a piece in The Hollywood Reporter "A scan was taken from a drone and used as the basis for a CG model of the location, which was augmented with VFX and joined with volcanic hills that were photographed in Iceland.

"[9] Spain-based El Ranchito, one of several special effects companies used by Game of Thrones, was responsible for the White Walker army shots.

The Night King also observes Jon destroying a White Walker with his Valyrian steel sword Longclaw, appearing intrigued at the sign of resistance.

[12] The Night King appears in a vision being observed by Bran and the Three-eyed Raven, where they witness him as a human being forcibly transformed into the first White Walker by the Children of the Forest by impaling him with a dragonglass dagger.

The Night King keeps his gaze on an enraged Jon, who appears on the verge of calling him down to fight directly, but his lieutenant hands him another spear.

[16] The undead army arrives at Eastwatch; when the Night King appears, riding Viserion, Tormund orders the defenders to evacuate.

Breathing blue fire, Viserion destroys Eastwatch and a section of the Wall, allowing the White Walkers and their wight army to finally invade the Seven Kingdoms while the Night King flies overhead towards the North.

[17] Led by the Night King, the dead quickly advance south and attack Last Hearth, massacring the population and adding them to their army, before marching on Winterfell.

Bran, knowing that the Night King intends to destroy him, plans to hide in Winterfell's Godswood as bait, with Jon and Daenerys lying in wait with the dragons to ambush him.

However, before he can kill Bran, he is ambushed by Arya Stark, who destroys him by plunging a dagger made out of Valyrian steel into the Night King's chest.

Top: Vladimír Furdík as the Night King with only practical effects and prosthetics.
Bottom: Added VFX in post-production, with altered eyes and an icy layer.