Mitov parted ways with the "blues" on 12 July 2013, following the team's elimination by Kazakh club Irtysh Pavlodar in the UEFA Europa League.

[4] In early December 2013, Mitov was announced as the new manager of PFC Montana in the B PFG on a contract until 30 June 2014.

[6] Mitov was appointed as manager of Botev Plovdiv on 30 August 2016, but decided to resign a few hours later due to a hostile reception from the fans.

[8] After five months of stay, PFC Levski and Nikolay Mitov decided to split by mutual agreement due to poor results.

Instead he returned in charge of Septemvri Sofia after the bad start of the team under Dimitar Vasev's tenure.