Organolanthanide chemistry

Organolanthanide compounds are different from their organotransition metal analogues in the following ways: Metal-carbon σ bonds are found in alkyls of the lanthanide elements such as [LnMe6]3− and Ln[CH(SiMe3)2]3.

Today, organolantanide chemistry continues to grow, emphasizing sustainability, advanced materials for electronics and photonics, and potential applications in biological and medicinal contexts.

[6] Their high color purity and near-unity quantum yields make them essential in photonic and display technologies, including advanced lighting, defense systems, magnets, bio-markers, and electronics.

Organolanthanide complexes are gaining attention for their energy efficiency, cost-effectiveness, and growing role in analyte detection, emphasizing their increasing importance in modern, high-performance systems.

While organolanthanide complexes have shown considerable promise in fields like catalysis and luminescence, several significant challenges limit their widespread application.

[4] The lanthanide ions in these complexes can readily react with oxygen and water, leading to oxidation or hydrolysis, which damages the material’s structure and reduces its efficiency.