Carolina Ardohaín was born on 17 January 1978[6] in General Acha, La Pampa, Argentina: she was one of very few people baptised at the monastery of Nuestra Señora del Pilar in Recoleta, Buenos Aires.

[10][11][12][13] Pampita on 22 November 2019[14] married the gastronomic entrepreneur Roberto García Moritan;[15] the couple has a daughter.

In March 2022, she host the program El hotel de los famosos, together with Leandro Leunis, in eltrece.

In 2005 Pampita starred in the Argentine romantic telenovela Doble vida with the role of Ema, who is the first of co-protagonists.

Pampita made her cinema debut in the 2009 Chilean film Súper, todo Chile adentro with the secondary role of Camila Hudson.