[3] In the 2000 FA Women's Cup Final at Bramall Lane, Cope saved a penalty kick from her England teammate Karen Walker as Croydon beat Doncaster Belles 2–1.
Having watched his side score a late winner in extra time, Arsenal manager Vic Akers declared: "Pauline Cope was absolutely outstanding.
[9] After her final game, a 1–0 defeat at Everton which consigned Charlton to third place in the table, club captain Casey Stoney said of Cope: "If I'm honest I don't think she can be replaced.
"[10] Cope played 60 times for the senior England women's national football team, making her debut in a 1–1 friendly draw with Italy in Florence on 26 January 1995.
[11] By the time of the 1995 FIFA Women's World Cup, held in Sweden during June 1995, she had displaced former Millwall teammate Lesley Higgs as England's first choice goalkeeper.
At the tournament it was reported that Cope's performances in comprehensive defeats by Norway and Germany had averted "hideous embarrassment" for the outmatched English team.
"[13] In October 2000, goalkeeping understudy Rachel Brown played in the UEFA Women's Euro 2001 qualification play-off in Ukraine when Cope was struck down with a stomach complaint on the morning of the game.