Pocket protectors were originally made of polyvinyl chloride (PVC).
The pocket protector was invented during World War II by Hurley Smith while he was working in Buffalo, New York.
[1] A competing claim for the invention came from Long Island plastics magnate Gerson Strassberg around 1952.
A more general market soon arose, made up of students, engineers, and white-collar workers in a variety of fields.
They have become part of a "nerd" or "geek" fashion stereotype, probably because of their association with engineers or students.