Process function

As an example, mechanical work and heat are process functions because they describe quantitatively the transition between equilibrium states of a thermodynamic system.

Examples of path functions include work, heat and arc length.

In other words, for a holonomic process function, λ may be defined such that dY = λδX is an exact differential.

For example, thermodynamic work is a holonomic process function since the integrating factor λ = ⁠1/p⁠ (where p is pressure) will yield exact differential of the volume state function dV = ⁠δW/p⁠.

The second law of thermodynamics as stated by Carathéodory essentially amounts to the statement that heat is a holonomic process function since the integrating factor λ = ⁠1/T⁠ (where T is temperature) will yield the exact differential of an entropy state function dS = ⁠δQ/T⁠.