She was the daughter of Alexander McCorquodale and the romantic novelist and socialite Barbara Cartland and the stepmother of Diana, Princess of Wales.
Her parents divorced in 1936, and her mother promptly married Alexander's cousin, Hugh McCorquodale, by whom she had two sons, Ian and Glen.
She had a successful season, not only being named debutante of the year, but becoming engaged to be married to the heir to an earldom, Gerald Humphry Legge.
At age 23, she became the youngest member of Westminster City Council as a Conservative, working from her home in Grosvenor Square.
She chaired the Covent Garden Development Committee and the government working party for the United Nations Conference on the Human Environment in Stockholm.
[4] In 1978, Lord Spencer suffered a brain haemorrhage; his wife nursed him, and his recovery is credited to her care and devotion coupled with the use of an untested drug.
[4] Following her husband's illness, Lady Spencer was widely criticised by the press and conservationists for her redecoration of Althorp, the Spencer family seat; it was felt that the heavy use of new gilding and wallpapers failed to compensate for the missing treasures which included, besides properties and land, works by Sir Anthony van Dyck and Thomas Gainsborough, furniture, china, porcelain, silver, gold, and family documents sold to fund the project and necessary restoration of the house.
"[2] Lord and Lady Spencer led an opulent lifestyle, entertaining frequently and generously, and travelling greatly.
Diana stood guard in person in the Spencer bedroom and watched as maid Pauline Shaw put the Countess's extensive clothing in four Louis Vuitton suitcases.
At Diana's instruction, the maid hastily unpacked the multi-piece designer wardrobe and instead stowed it in black garbage bags.
[9] During Diana's divorce from Prince Charles, she and Raine reportedly reconciled and grew closer, and the two were frequently photographed meeting for lunch.