It was written by Joleen Belle, Tyrice Jones, Kowan Paul, and Robyn Sykes and recorded for the group's debut album, Lickin' on Both Sides (2001), while production was helmed by Blacksmith.

The song was released as a double A-single along with a cover version of Montell Jordan's "This Is How We Do It" on 17 June 2002, marking the album's final single.

Upon its release, it became another top-10 success for the group on the UK Singles Chart, peaking at number seven.

The video opens with "Roll On", starting with a group of men playing basketball in a court.

Mis-Teeq members Alesha Dixon, Su-Elise Nash and Sabrina Washington arrive in a lowrider and watch the men play basketball, and occasionally join in.