With the introduction of the Greek sundial to Rome from the Samnites circa 293 BC, the period of the natural day from sunrise to sunset was divided into twelve hours.
[6] It was divided into the following parts: The natural day (dies naturalis) ran from sunrise to sunset.
[8] Despite rapidly gaining popularity soon after their introduction, it wouldn't be until 164 BC that the first sundial specifically designed for the city of Rome was constructed.
[11] The daytime canonical hours of the Catholic Church take their names from the Roman clock: the prime, terce, sext and none occur during the first (prīma) = 6 am, third (tertia) = 9 am, sixth (sexta) = 12 pm, and ninth (nōna) = 3 pm, hours of the day.
This was a period of prayer initially held at three in the afternoon but eventually moved back to midday for unknown reasons.