She married William IV, Count of Mâcon (d. 1224) in approximately 1183.
As part of her dowry Scholastique brought land as well as income from the fairs of Bar-sur-Aube.
The couple produced the following issue: Scholastique died in 1219 and was buried in collegiate church of Saint-Etienne in Troyes.
The church contained the tombs of Marie, Countess of Champagne, Henry I, Count of Champagne, Marie of Champagne, Henry II, and Theobald.
Her sister-in-law Countess-Regent Blanche of Navarre would later be buried there as well.