He spent his career in the Ukrainian Premier League Reserves club FC Metalurh Donetsk.

In July 2015 Napolov signed a contract with FC Metalist and was promoted to the Ukrainian Premier League's squad.

He made his debut for Metalist Kharkiv in the Ukrainian Premier League in a match against FC Stal Dniprodzerzhynsk on 24 April 2016.

[4] On 4 August 2020, he joined Chojniczanka Chojnice in the Polish third-tier II liga.

This biographical article related to a Ukrainian association football midfielder born in the 1990s is a stub.