The sheer is a measure of longitudinal main deck curvature in naval architecture.
Increases in the rise of the sheer forward and aft build volume into the hull, and in turn increase its buoyancy forward and aft, thereby keeping the ends from diving into an oncoming wave and slowing the ship.
In the early days of sail, one discussed a hull's sheer in terms of how much "hang" it had.
William Sutherland's The Ship-builders Assistant (1711) covers this information in more detail.
These vessels were built with the decks curving upwards at the bow and stern in order to increase stability by preventing the ship from pitching up and down.