The show features Iron Chef Mario Batali, actress Gwyneth Paltrow, New York Times food writer Mark Bittman, and Spanish actress Claudia Bassols.

Each episode covers a different region of Spain as the foursome explore the country's culinary traditions and history.

In October 2008, HarperCollins published a hardcover companion book, Spain… A Culinary Road Trip (ISBN 978-0-06-156093-4, OCLC 191930257), written by Batali, Paltrow, and Julia Turshen.

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