Her siblings Roy, Ian, Quentin, Chris and Deb have all been notably involved in media, television and film.
[citation needed] From 1983 to 2000, Masters worked at the Australian Broadcasting Corporation (ABC).
During her career, Masters has produced and executive produced multi-award-winning drama series, including Brides of Christ, SeaChange, The Road from Coorain and Changi.
Under her stewardship, successful series The Secret Life of Us and White Collar Blue were commissioned.
Masters features in a 2011 Australian Story episode that details her work with members of the controversial Bra Boys "gang" Macario De Souza, Richie Vaculik and Mark Mathews.