[4][5] Salgueiro joined Madredeus after other members noticed her singing at a bar in Lisbon.

[6][7] She left Madredeus in November 2007 to focus on solo work.

[8][9] In 2007, Salgueiro performed a concert of Neapolitan music at the Teatro di San Carlo with the Solis String Quartet.

[10] In the same year, she released Você e Eu with Septeto de João Cristal; in this album, Salgueiro covers songs from well-known Brazilian artists such as Chico Buarque and Vinicius de Moraes.

[11][12] In 2021, Salgueiro featured in two songs of Patrick Watson's singles album.