The characters within the narrative segments included Mysti (Laura Aikman), who is half-human and half-fairy; and her friends Rick (Oliver Mason), Ella (Eva Alexander), Ollie (Ashley Campbell), and Abby (Yasmin Paige).
Other characters also appeared frequently, such as Professor Dust (David Sterne) and Tatiana (Tricia George), fairies Snowdrop (Amy Pemberton) and Peaceblossom (Danielle Tabor), and diner owner Mr. K (Richard James).
Mysti, Rick, Ella, and Ollie would also appear, in character, as the presenters of the magazine segments of the show.
Many well-known faces appeared as guests on the show, including Jackie Chan, Steve Coogan, Kirsten Dunst, McFly, and Jamelia.
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