The album was released in two different editions, standard and limited, with the latter containing two remixes incorporates elements of Rubio's earlier singles.

The compilation album reached number thirty in Spain, despite receiving promotion from the singer.

The album consists with thirteen greatest hits from Rubio's first records: "Mío", "Amor De Mujer", and "Sabor A Miel" from La Chica Dorada (1992); "Nieva, Nieva", "Él Me Engañó", and "Asunto De Dos" from 24 Kilates (1993); "Te Daría Mi Vida", "Nada De Ti", "Hoy Te Dejé De Amar", and "Bésame En La Boca" from El Tiempo Es Oro (1995); and, "Siempre Tuya Desde La Raíz", "Solo Por Ti", and "Enamorada" from Planeta Paulina (1996).

The "energetic and rhythmic"[2] final tracks "Megahits" incorporates elements of Rubio's biggest hit singles remix by DJ Eduardo Posadas.

Drago Bonacich of Allmusic opined that the collection of greatest hits "comprising more than a decade of romantic ballads and dance/pop songs", and explained "Top Hits brings Paulina Rubio's best, before crossing over with her first English-language single called "Sexual Lover".