On 5 August 1948,[1][2] Naydyonova was born in the village of Zaozerne [uk] in the Kherson Oblast, Kakhovka Raion.
[4] From 1966 to 1968, Naydyonova worked as a accountant and cashier at Tavrychan village council in Kakhovka, Kherson Oblast.
[4] Naydyonova was appointed secretary of the Askani state farm of the Kakhovka district's party committee from 1984 to 1985.
[5][7] This led the farm to become one of the best in the Kherson Oblast and of the National Academy of Agrarian Sciences of Ukraine [uk] system.
[8] She received the Order of Princess Olga, Third Class from Leonid Kuchma on 19 August 1998 "For a significant personal contribution to the formation of Ukrainian statehood, merits in the socio-economic, scientific, technical and cultural development of Ukraine and on the occasion of the 7th anniversary of Ukraine's independence".
[9] She was upgraded to Order of Princess Olga, Second Class by Kuchma on 21 August 2001 "For significant personal contribution to the socio-economic and cultural development of Ukraine, significant labor achievements and on the occasion of the 10th anniversary of Ukraine's independence".