The settlement Hajduki was established in the late 16th or early 17th century when the local area belonged to the Habsburg monarchy.

In the War of the Austrian Succession most of Silesia was conquered by the Kingdom of Prussia, including the village.

In 1873 the steel mill „Bismarckhütte” was opened (in 1933 renamed to „Huta Batory”) and other industrial establishment, as well as the population growth, followed.

In the years 1898-1901 the Roman Catholic Saint Mary's church was built, a seat of a separate parish since 1908.

The official change of the name from Bismarckhütte to Hajduki Wielkie took place on 19 June 1922.