Originally from Ukraine, Samadova started her professional career at Rabita Baku in 2014.

In summer of 2017, she transferred to the Italian Serie A1 team, Pallavolo Scandicci.

She helped her team earn gold at the 2016 Women's European Volleyball League and 2017 Islamic Solidarity Games.

She also played for Azerbaijan in the 2017 Women's European Volleyball Championship and reached the semifinals.

Samadova is dating Jovan Krneta, Serbian professional football player who currently plays for Zira FK in Azerbaijani Premier League.