Although failing to pre-qualify, Gregor Foitek had one of his better sessions, finishing sixth fastest in the sole EuroBrun, ahead of the Osella of Nicola Larini, who suffered a fuel pump issue.
Coloni had only brought three mechanics and one car for both Raphanel and Roberto Moreno, while waiting for their new C3 to be built, making a token effort to qualify in order to comply with the regulations and avoid a fine.
[1] In qualifying proper, World Champion Ayrton Senna scored his 33rd career pole position, equalling the long-standing record held by Jim Clark.
Mansell's teammate Gerhard Berger, returning to action in Mexico after his crash at San Marino, was sixth, the Ferraris split by the March-Judd of Ivan Capelli and the Williams-Renault of Riccardo Patrese.
Berger, still suffering the effects of his crash, admitted that if not for Ferrari's innovative semi-automatic transmission (which meant he did not have to change gears as with a normal stick shift), he would not have been able to race.
The back row of the grid was arguably the best credentialed and most experienced in Grand Prix history, consisting of seven-time winner René Arnoux in the Ligier-Ford and triple World Champion Nelson Piquet in the Lotus-Judd.
Despite the pole being on the dirty side of the track in Mexico, Senna made a better start and was able to lead into the first turn from Mansell, Prost, Berger, Patrese and the Tyrrell-Ford of Michele Alboreto.