Clubs that qualify for the 2013 Copa Libertadores entered the competition in the Round of 16.
The best 8 teams of 2012 Campeonato Brasileiro eliminated up to the third round qualifies for 2013 Copa Sudamericana which was contested in the second half of 2013.
[2] The competition is a single elimination knockout tournament featuring two-legged ties.
[2] Teams in bold qualified for 2013 Copa Libertadores and entered directly in the Round of 16.
A draw by CBF scheduled for August 6 set the matches for this round.