Her eldest brother Peter became the Latin emperor of Constantinople in 1216.

Alice's first husband was Andrew, lord of La Ferté-Gaucher, Champagne, whom she married some time after 1169.

[3] The marriage produced one surviving child, Peter, later count of Joigny, (d.1222).

A charter dated 1180 records that Count William, with Alice's consent, donated property to Pontigny Abbey.

Aymer died on 16 June 1202 and was succeeded by their daughter, Isabella.