In 2007, Duro started her career with fifteen years in the Spanish television series Cuestión de sexo.

[citation needed] From 2008 to 2011, she rose to fame with her role as Yolanda "Yoli" Freire Carballar in the Spanish television series Física o Química.

[citation needed] In 2016, she had a cast appearance with Ruth Núñez in the ninth season of La que se avecina.

[3] In January 2019, it was ended the filming of the TV series Promesas de arena, starring Andrea Duro and Blanca Portillo.

[4] In 2020, it is confirmed that the actress will give life to Yolanda "Yoli" Freire Carballar in Física o químicaː El reencuentro for the platform Atresplayer Premium, where she and Maxi Iglesias are the protagonists.