The young defender was part of a very elite youth set-up alongside the likes of Domenico Criscito, Paolo De Ceglie, Davide Lanzafame, Claudio Marchisio, Michele Paolucci, Sebastian Giovinco, and Dario Venitucci, all of which have represented Italy at various stages of international football.
On 30 June 2009 Pisani returned to Juventus; in July a deal to move on loan again to Lega Pro Prima Divisione side A.C. Arezzo was finalized but was immediately cancelled.
On 1 July 2010 he again returned to Juventus, but did not train with the club's first team, and was not called up to the UEFA Europa League squad by then coach, Luigi Delneri.
Pisani was then loaned out to Serie B newcomers, Calcio Portogruaro Summaga, alongside Salvatore D'Elia.
Following a poor campaign for club and player, Pisani was sold in a co-ownership deal to third-tier side, S.S. Barletta Calcio ahead of the 2011-12 Lega Pro Prima Divisione season.